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Give a simple chemical test to distinguish between propanal and propanone.

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The Tollens' test is a classic test to identify aldehydes. Aldehydes reduce silver ions to form a silver mirror, while ketones do not react.
Updated On: Feb 28, 2025
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Solution and Explanation

A simple chemical test to distinguish between propanal (an aldehyde) and propanone (a ketone) is the Tollens' test.
Propanal (Aldehyde): On treatment with Tollens' reagent (ammoniacal silver nitrate), aldehydes reduce the silver ions to metallic silver, forming a silver mirror on the inner surface of the test tube.
Propanone (Ketone): Ketones do not react with Tollens' reagent and hence do not produce the silver mirror.
Thus, the Tollens' test can distinguish between an aldehyde and a ketone.
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