A primary amine is an organic compound with the functional group \( -NH_2 \), where one hydrogen atom of ammonia is replaced by an alkyl or aryl group. Among the options, \( \text{Ethylamine} \) has the structure \( \text{CH}_3\text{CH}_2\text{NH}_2 \), which contains the \( -NH_2 \) group, making it a primary amine. Other options such as \( \text{Diethylamine} \) and \( \text{Triethylamine} \) are secondary and tertiary amines, respectively, and \( \text{Aniline} \) contains an aromatic \( -NH_2 \) group.