From the following identify pairs in which metal is correctly matched with its refining process:

Understanding each metal's refining process:
A. Zn - Distillation: Zinc is refined by distillation due to its low boiling point, separating it from impurities with higher boiling points.
B. Sn - Liquation: Tin is refined using liquation, where impurities with different melting points are separated by heating the metal.
C. Ga - Zone refining: Gallium is refined by zone refining, where a molten zone moves along the metal, effectively purifying it by removing impurities.
D. Zr - Vapour phase refining: Zirconium is refined using vapour phase refining, where it reacts with chlorine to form ZrCl4, which is then distilled. Thus, all the given pairs are correct.
Given below are some nitrogen containing compounds:
Each of them is treated with HCl separately. 1.0 g of the most basic compound will consume ...... mg of HCl.
(Given Molar mass in g mol\(^{-1}\): C = 12, H = 1, O = 16, Cl = 35.5.)

Given below are some nitrogen containing compounds:
Each of them is treated with HCl separately. 1.0 g of the most basic compound will consume ...... mg of HCl.
(Given Molar mass in g mol\(^{-1}\): C = 12, H = 1, O = 16, Cl = 35.5.)

Match the following with their pKa values 
At T(K), the value of \( K_c \) for the reaction
\[ AO_2(g) + BO_2(g) \leftrightarrow{} AO_3(g) + BO(g) \] is 16. In a one-litre closed flask, 1 mole each of \( AO_2(g) \), \( BO_2(g) \), \( AO(g) \), and \( BO(g) \) were taken and heated to T(K).
What are the equilibrium concentrations (in mol L\(^{-1}\)) of \( BO_2(g) \) and \( BO(g) \) respectively?
At equilibrium for the reaction $ A_2 (g) + B_2 (g) \rightleftharpoons 2AB (g) $, the concentrations of $ A_2 $, $ B_2 $, and $ AB $ respectively are $ 1.5 \times 10^{-3} M $, $ 2.1 \times 10^{-3} M $, and $ 1.4 \times 10^{-3} M $. What will be $ K_p $ for the decomposition of $ AB $ at the same temperature?
The molar heats of fusion and vaporization of benzene are 10.9 and 31.0 kJ mol\(^{-1}\) respectively. The changes in entropy for the solid \(\rightarrow\) liquid and liquid \(\rightarrow\) vapor transitions for benzene are \(x\) and \(y\) J K\(^{-1}\) mol\(^{-1}\) respectively. The value of \(y(x)\) in J\(^2\) K\(^{-2}\) mol\(^{-2}\) is: