Question:

Four curves designated as I, II, III, and IV are shown in the figure. \(P_b\) is the bubble point pressure of a crude oil at the given temperature. Which ONE of the following options correctly depicts the solubility of asphaltene (\(q_a\)) in the crude oil with pressure (\(P\)) at a given temperature? \begin{center} \includegraphics[width=0.7\textwidth]{03.jpeg} \end{center}

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Asphaltene solubility depends strongly on pressure relative to the bubble point. Instability occurs near the bubble point, where precipitation is most likely.
Updated On: Aug 24, 2025
  • I
  • II
  • III
  • IV
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The Correct Option is B

Solution and Explanation


Step 1: Recall asphaltene solubility behavior.
- At high pressures (above bubble point \(P_b\)), asphaltenes are stable and remain dissolved in crude oil. - As pressure decreases towards \(P_b\), solubility decreases, and precipitation risk increases. - Below \(P_b\), gas liberation reduces solvency power, decreasing solubility further. Step 2: Interpret curves.
- Curve I (horizontal) suggests no change with pressure → unrealistic. - Curve II (U-shaped): high solubility at high \(P\), minimum near \(P_b\), then increase again due to lighter fractions vaporizing → matches known behavior. - Curve III and IV do not follow known asphaltene solubility trends. Step 3: Conclusion.
The correct curve is \(II\). Final Answer: \[ \boxed{\text{II}} \]
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