For the reaction:
\(2A + B → A_2B\)
the rate = k[A][B]2 with k= 2.0 x 10-6 mol-2L2s-1. Calculate the initial rate of the reaction when [A] = 0.1 mol L-1, [B] = 0.2 mol L-1. Calculate the rate of reaction after [A] is reduced to 0.06 mol L-1.
The initial rate of the reaction is
Rate = k [A][B]2
Rate = (2.0 × 10-6 mol-2L2 s-1) (0.1 mol L-1) (0.2 mol L-1)2
Rate = 8.0 × 10-9 mol-2L2s-1
When [A] is reduced from 0.1 mol L-1 to 0.06 mol-1, the concentration of A reacted = (0.1 - 0.06) mol L-1 = 0.04 mol L-1
Therefore, concentration of B reacted = \(\frac 12\) x 0.04 mol L-1
Then, concentration of B available, [B] = (0.2 - 0.02) mol L-1
[B] = 0.18 mol L-1
After [A] is reduced to 0.06 mol L-1 , the rate of the reaction is given by
Rate = k [A][B]2
Rate = (2.0 × 10-6 mol-2L2s-1) (0.06 mol L-1 ) (0.18 mol L-1 )2
Rate = 3.89 mol L-1s-1
The rate of a chemical reaction is defined as the change in concentration of any one of the reactants or products per unit time.
Consider the reaction A → B,
Rate of the reaction is given by,
Rate = −d[A]/ dt=+d[B]/ dt
Where, [A] → concentration of reactant A
[B] → concentration of product B
(-) A negative sign indicates a decrease in the concentration of A with time.
(+) A positive sign indicates an increase in the concentration of B with time.
There are certain factors that determine the rate of a reaction: