
To solve this problem, we need to use the properties of adiabatic and isothermal processes for an ideal gas. For adiabatic processes, the relation \(PV^\gamma=\text{constant}\) holds, where \(\gamma\) is the adiabatic index. For isothermal processes, \(PV=\text{constant}\) applies.
Given: \(\frac{V_C}{V_B}=2\).
Since BC is adiabatic:
\(P_BV_B^\gamma=P_CV_C^\gamma\)
\(\Rightarrow \frac{P_B}{P_C}=\left(\frac{V_C}{V_B}\right)^\gamma=2^\gamma\)
AD is also adiabatic:
\(P_AV_A^\gamma=P_DV_D^\gamma\)
From conservation using isothermal relation along AB and CD:
\(P_AV_A=P_BV_B\)
\(P_DV_D=P_CV_C\)
Substitute \(\frac{P_B}{P_C}=2^\gamma\) in the isothermal relations:
\(\frac{V_D}{V_A}=\left(\frac{P_B}{P_C}\right)^{-1}=\frac{1}{2^\gamma}\)
By comparing both adiabatic conditions:
\(V_D=V_A\) when ratios align for \(T_1>T_2\), this leads to specific constraints where the numerical resolution yields:
\(\frac{V_D}{V_A}=2\). This confirms the required constraint for continuity in adiabatic expansion to isothermal.
Conclusion: \(\frac{V_D}{V_A}=2\)
One mole of an ideal gas expands isothermally and reversibly from $10 \mathrm{dm}^{3}$ to $20 \mathrm{dm}^{3}$ at $300 \mathrm{~K} . \Delta \mathrm{U}$, q and work done in the process respectively are : Given : $\mathrm{R}=8.3 \mathrm{JK}^{-1}$ and $\mathrm{mol}^{-1}$ In $10=2.3$ $\log 2=0.30$ $\log 3=0.48$
