In the spin singlet state, the total spin of the system is zero, and the spin operators \( \sigma_1 \) and \( \sigma_2 \) for the two particles are related by:
\[
\sigma_1 \cdot \sigma_2 = -1.
\]
Thus, the value of \( \sigma_1 \cdot \sigma_2 \) is \( -3 \).