Question:

Fluorine molecule has bond order one. The number of electrons in the ant bonding molecular orbitals is two less than that in bonding molecular orbitals.

Updated On: Jun 23, 2023
  • If both Assertion and Reason are true and the Reason is the correct explanation of the Assertion
  • If both Assertion and Reason are true but the reason is not the correct explanation of the Assertion
  • If Assertion is true but Reason is false
  • If both Assertion and Reason are false
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The Correct Option is A

Solution and Explanation

MO electronic configuration of $F _{2}$ molecule is $F _{2}=\sigma 1 s^{2}, \sigma^{*} 1 s^{2}, \sigma 2 s^{2}, \sigma^* 2 s^{2}, \sigma 2 p_{x}^{2}, $ $ \pi 2 p_{y}^{2} \approx \pi 2 p_{z}^{2}, \pi^{*} 2 p_{y}^{2} \approx \pi^* 2 p_{z}^{2} $ Bond order $=\frac{N_{b}-N_{a}}{2}$ where, $N_{b}=$ Number of electrons in bonding molecular orbitals $N_{a}=$ Number of electrons in antibonding molecular orbitals $=\frac{8-6}{2}=1$
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Concepts Used:

Molecular Orbital Theory

The Molecular Orbital Theory is a more sophisticated model of chemical bonding where new molecular orbitals are generated using a mathematical process called Linear Combination of Atomic Orbitals (LCAO).

Molecular Orbital theory is a chemical bonding theory that states that individual atoms combine together to form molecular orbitals. Due to this arrangement in MOT Theory, electrons associated with different nuclei can be found in different atomic orbitals. In molecular orbital theory, the electrons present in a molecule are not assigned to individual chemical bonds between the atoms. Rather, they are treated as moving under the influence of the atomic nuclei in the entire molecule

Molecular Orbital Theory
Molecular Orbital Theory