Step 1: Examine Option A - "Recieve''
"Recieve'' is incorrect. The correct spelling is "receive'', following the "i before e except after c'' rule.
Step 2: Examine Option B - "Desiccate''
"Desiccate'' is correctly spelled. It means to remove moisture.
Step 3: Examine Option C - "Exquisite''
"Exquisite'' is correctly spelled. It means extremely beautiful and delicate.
Step 4: Examine Option D - "Imminent''
"Imminent'' is correctly spelled. It means about to happen.
Thus, the misspelled word is Option A: "Recieve'' $\rightarrow$ "Receive''.