Question:

F-centres in an ionic crystal are

Updated On: Aug 25, 2023
  • lattice sites containing electrons
  • interstitial sites containing electrons
  • lattice sites that are vacant
  • intertitial sites containing cations
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F-centers are lattice sites containing electrons. It is a crystallographic defect. In this electron fills the anionic vacancy generated. 

Read more from chapter: Solid State 

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Real Life Applications

F centers are used to form: 

  • Lasers, that produce light of a single wavelength.
  • Scintillators will generate electrical signals from light sources. They are used in medical imaging.
  • Phosphors form light when exposed to certain radiation.
  • F center absorbs light from the visible region and therefore acts as a coloring agent.
Scintillators will generate electrical signals from light sources. They are used in medical imaging.

Question can also be asked as

  • What are f centers?
  • What are the properties of the f center?
  • How are f centers formed?
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Crystals are not perfect, even though they have short-range and long-range orders of arrangement. Here are four types of defects observed in crystals. They are as follows:

  • Point defect
  • Line defect
  • Volume defect
  • Surface defect

Point defect 

Point defects occur around a particle or an atom. It occurs only at a single lattice point. These are the smallest defect that occurs in a lattice. They occur when:

  • If a foreign atom occupies the position in the crystal lattice.
  • The original atom is replaced by a foreign atom.
  • One or more atoms are missing from their lattice site.
  • If there is a shift in the atom from its original place.

Types of point defects 

There are five types of point defects:

  1. Stoichiometric defects
  2. Schottky defect
  3. Frenkel defect
  4. Impurity defect
  5. Non- Stoichiometric defects

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Related concepts 
Solid Crystal Lattice Frenkel defect 
Close packing Covalent bond Metal deficiency defect 
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Concepts Used:

Solid State

Solids are substances that are featured by a definite shape, volume, and high density. In the solid-state, the composed particles are arranged in several manners. Solid-state, in simple terms, means "no moving parts." Thus solid-state electronic devices are the ones inclusive of solid components that don’t change their position. Solid is a state of matter where the composed particles are arranged close to each other. The composed particles can be either atoms, molecules, or ions. 

Solid State

Types of Solids:

Based on the nature of the order that is present in the arrangement of their constituent particles solids can be divided into two types;

  • Amorphous solids behave the same as super cool liquids due to the arrangement of constituent particles in short-range order. They are isotropic and have a broad melting point (range is about greater than 5°C).
  • Crystalline solids have a fixed shape and the constituent particles are arranged in a long-range order.