Question:

Extraction of gold and silver involes leaching with $CN^-$ ion. Silver is later recovered by :-

Updated On: Jul 18, 2024
  • distillation
  • zone refining
  • displacement with Zn
  • liquation
Hide Solution
collegedunia
Verified By Collegedunia

The Correct Option is C

Solution and Explanation

Zn is more reactive than Ag and Au, therefore Zn will displace them.

From Native ore,

$4 Ag +8 NaCN +2 H _{2} O + O _{2} \stackrel{\text { Leaching }}{\longrightarrow} \underset{\text{Soluble Sodium dicyanoargentate(I)}}{4Na [Ag(CN)_2]} + 4 Na OH$
$2 Na \left[ Ag ( CN )_{2}\right]+ Zn \stackrel{\text { Displacement }}{\longrightarrow} Na _{2}\left[ Zn ( CN )_{4}\right]+2 Ag \downarrow$
Was this answer helpful?
0
0

Top Questions on General Principles and Processes of Isolation of Elements

View More Questions

Concepts Used:

General Principles and Processes of Isolation of Elements

What are Ores and Minerals? 

Minerals are the naturally occurring, homogeneous inorganic solid substances. They are having a definite chemical composition and crystalline structure, hardness and color. For example, copper pyrite, calamine, etc.

Impurities in an ore are called gauge. The removal of a gauge from the ore is called concentration ore. 

Several steps are involved in the extraction of pure metal from ores. Major steps are as follows –

  • Concentration of the ore
  • Isolation of the metal from its concentrated ore
  • Purification of the metal