Step 1: Use the formula for work done in adiabatic expansion of a diatomic gas: \[ W = \frac{n R \Delta T}{\gamma - 1} \] For a diatomic gas, \( \gamma = \frac{7}{5} \Rightarrow \gamma - 1 = \frac{2}{5} \)
Step 2: Given: \( n = 3 \), \( \Delta T = -50^\circ\text{C} = -50\,\text{K} \) \[ W = \frac{3 R (-50)}{2/5} = -75R \cdot \frac{5}{2} = -187.5R \] The work done by the gas is positive during expansion, so magnitude is: \[ W = 187.5R \times 2 = 375R \]
A hot plate is placed in contact with a cold plate of a different thermal conductivity as shown in the figure. The initial temperature (at time $t = 0$) of the hot plate and cold plate are $T_h$ and $T_c$, respectively. Assume perfect contact between the plates. Which one of the following is an appropriate boundary condition at the surface $S$ for solving the unsteady state, one-dimensional heat conduction equations for the hot plate and cold plate for $t>0$?

The following data is given for a ternary \(ABC\) gas mixture at 12 MPa and 308 K:

\(y_i\): mole fraction of component \(i\) in the gas mixture
\(\hat{\phi}_i\): fugacity coefficient of component \(i\) in the gas mixture at 12 MPa and 308 K
The fugacity of the gas mixture is _________ MPa (rounded off to 3 decimal places).
The internal energy of air in $ 4 \, \text{m} \times 4 \, \text{m} \times 3 \, \text{m} $ sized room at 1 atmospheric pressure will be $ \times 10^6 \, \text{J} $. (Consider air as a diatomic molecule)