Draw the structures of optical isomers of:
(i) \([Cr(C_2O_4)_3]^{3–}\)
(ii) \([PtCl_2(en)_2]^{2+}\)
(iii) \([Cr(NH_3)2Cl_2(en)]^{+}\)
Draw the structures of optical isomers of:
(i) \([Cr(C_2O_4)_3]^{3–}\)
(ii) \([PtCl_2(en)_2]^{2+}\)
(iii) \([Cr(NH_3)2Cl_2(en)]^{+}\)
Solution and Explanation
(i) \([Cr(C_2O_4)_3] ^{3-}\)
(ii) \([PtCl_2(en)_2]^{ 2+}\)
(iii)\( [Cr(NH_3)_2Cl_2(en)]^{+}\)
Top Questions on Coordination Compounds
The correct IUPAC name of \([ \text{Pt}(\text{NH}_3)_2\text{Cl}_2 ]^{2+} \) is:
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What type of isomerism is shown by the complex \([\text{Co(NH}_3)_6][\text{Cr(CN)}_6]\)?
The given coordination compound \([\text{Co(NH}_3)_6][\text{Cr(CN)}_6]\) exhibits ionization isomerism.
**Explanation:** Ionization isomerism arises when two complexes have the same molecular formula but yield different ions in solution. In this case, the cationic complex \([\text{Co(NH}_3)_6]^{3+}\) and the anionic complex \([\text{Cr(CN)}_6]^{3-}\) could interchange their ligands under different conditions, leading to a different complex with distinct properties.
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(a)[Fe(en)2Cl2]+
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Concepts Used:
Isomerism in Coordination Compounds
Isomers in Coordination Compounds
Stereoisomers occur when the ligands have the same bonds, but the bonds are in different orientations relative to one another. Structural isomerism occurs when the bonds are different. Isomers are distinct compounds that can have different physical properties such as color, crystal structure, and melting point.
Cis and Trans Stereoisomers
In octahedral complexes—with four of one ligand and two of another—and square planar complexes—with two of one ligand and two of another—there are two different arrangements of the same atoms with the same bonds. These different arrangements are called cis and trans. In cis molecules, the two ligands are on the same side of the complex. In trans molecules, the similar ligands are on the opposite sides of the molecules, meaning the bond angle is 180 degrees.
Optical Stereoisomers
Optical isomerism occurs when a molecule is not superimposable with its mirror image.
Fac and Mer Stereoisomers
When three identical ligands occupy one face of an octahedron, the isomer is said to be facial or fac. If these three ligands and the metal ion are in one plane, the isomer is said to be meridional or mer.