To match the monosaccharides with their respective epimers, we need to identify the epimers of the given monosaccharides based on the carbon position at which the difference occurs.
Step 1: D-Mannose
D-Mannose is an epimer of D-Glucose at C-2. This means the epimer of D-mannose is the C-4 epimer of D-glucose.
Thus, \( P \) matches with 4.
Step 2: D-Allose
D-Allose is the C-3 epimer of D-Glucose.
Thus, \( Q \) matches with 1.
Step 3: D-Galactose
D-Galactose is the C-4 epimer of D-Glucose.
Thus, \( R \) matches with 2.
Step 4: D-Talose
D-Talose is the C-4 epimer of D-Mannose.
Thus, \( S \) matches with 3.
Final Answer:
The correct answer is \( \boxed{A} \).