C$_2H_2$ have acidic nature but it is less acidic than water but phenol is more acidic than water due to resonance stabilisation of phenoxide ion. H$_2CO_3$ is most acidic due to resonating stabilisation of carbonate ion (CO$_3^{2-}$). Thus, the correct order is $ \, \, \, \, \, \, C_2H_2 < H_20 < phenol < H_2CO_3$
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Top Questions on Organic Chemistry - Some Basic Principles and Techniques