Step 1: Understanding water of crystallisation:
Water of crystallisation refers to the water molecules that are chemically bound within the crystalline structure of a compound. These water molecules are an integral part of the crystalline form of the substance.
Step 2: Analyzing the given compounds:
- FeSO4 (Iron(II) sulfate) can form hydrated compounds like FeSO4·7H2O, meaning it contains 7 molecules of water of crystallisation in one molecule.
- CuSO4 (Copper(II) sulfate) commonly forms CuSO4·5H2O, which contains 5 molecules of water of crystallisation.
- CaSO4 (Calcium sulfate) typically forms CaSO4·2H2O, containing 2 molecules of water of crystallisation.
- Na2CO3 (Sodium carbonate) forms Na2CO3·10H2O, containing 10 molecules of water of crystallisation.
Step 3: Conclusion:
Among the given compounds, FeSO4 forms a crystalline compound with 7 molecules of water of crystallisation in one molecule, which is the highest among the listed compounds. Therefore, the correct answer is FeSO4.