Cobalt chloride when dissolved in water forms pink colored complex $X$ which has octahedral geometry. This solution on treating with cone $HCl$ forms deep blue complex, $\underline{Y}$ which has a $\underline{Z}$ geometry $X, Y$ and $Z$, respectively, are
Cobalt chloride when dissolved in water forms pink colored complex $X$ which has octahedral geometry. This solution on treating with cone $HCl$ forms deep blue complex, $\underline{Y}$ which has a $\underline{Z}$ geometry $X, Y$ and $Z$, respectively, are
- $X =\left[ Co \left( H _2 O \right)_4 Cl _2\right]^{+}, Y =\left[ CoCl _4\right]^{2-}, Z =$ Tetrahedral
- $X =\left[ Co \left( H _2 O \right)_6\right]^{2+}, Y =\left[ CoCl _6\right]^{3-}, Z =$ Octahedral
- $X =\left[ Co \left( H _2 O \right)_6\right]^{2+}, Y =\left[ CoCl _4\right]^{2-}, Z =$ Tetrahedral
- $X =\left[ Co \left( H _2 O \right)_6\right]^{3+}, Y =\left[ CoCl _6\right]^{3-}, Z =$ Octahedral
The Correct Option is C
Solution and Explanation
So, the correct answer is (C): X=[Co(H2O)6]2+,Y=[CoCl4]2−,Z= Tetrahedral
Top Questions on d -and f -Block Elements
- A first row transition metal with the highest enthalpy of atomisation, upon reaction with oxygen at high temperature, forms oxides of formula \( \text{M}_2\text{O}_n \) (where \( n = 3, 4, 5 \)). The 'spin-only' magnetic moment value of the amphoteric oxide from the above oxides is ___ BM (near integer).
(Given atomic number: \( \text{Sc: 21, Ti: 22, V: 23, Cr: 24, Mn: 25, Fe: 26, Co: 27, Ni: 28, Cu: 29, Zn: 30} \))- JEE Main - 2024
- Chemistry
- d -and f -Block Elements
- Match List-I with List-II.Choose the correct answer from the options given below:
List-I
Alkali MetalList-II
Emission Wavelength
in nm(A) Li (I) 589.2 (B) Na (II) 455.5 (C) Rb (III) 670.8 (D) Cs (IV) 780.0 - JEE Main - 2024
- Chemistry
- d -and f -Block Elements
- A first row transition metal in its +2 oxidation state has a spin-only magnetic moment value of 3.86 BM. The atomic number of the metal is
- JEE Main - 2024
- Chemistry
- d -and f -Block Elements
- The 'Spin only' Magnetic moment for \([Ni(NH_3)_6]^{2+}\) is _____ × \(10^{−1}\) BM. (given = Atomic number of Ni : 28)
- JEE Main - 2024
- Chemistry
- d -and f -Block Elements
- The compound that is white in color is
- JEE Main - 2024
- Chemistry
- d -and f -Block Elements
Questions Asked in JEE Main exam
- The area enclosed by the curves xy + 4y = 16 and x + y = 6 is equal to :
- JEE Main - 2024
- Area under Simple Curves
- A hydrogen atom changes its state from \( n = 3 \) to \( n = 2 \). Due to recoil, the percentage change in the wavelength of emitted light is approximately \( 1 \times 10^{-n} \). The value of \( n \) is ______. \([ \text{Given: } Rhc = 13.6 \, \text{eV}, \, hc = 1242 \, \text{eV nm}, \, h = 6.6 \times 10^{-34} \, \text{J s}, \, \text{mass of the hydrogen atom} = 1.6 \times 10^{-27} \, \text{kg} ]\)
- JEE Main - 2024
- Atomic Physics
- A closed organ pipe 150 cm long gives 7 beats per second with an open organ pipe of length 350 cm, both vibrating in fundamental mode. The velocity of sound is ________ m/s.
- Which figure shows the correct variation of applied potential difference (\(V\)) with photoelectric current (\(I\)) at two different intensities of light (\(I_1 < I_2\)) of same wavelengths:
- JEE Main - 2024
- Photoelectric Effect
- Let \( z \) be a complex number such that the real part of \[ \frac{z - 2i}{z + 2i} \] is zero. Then, the maximum value of \( |z - (6 + 8i)| \) is equal to:
- JEE Main - 2024
- complex numbers
Concepts Used:
D and F Block Elements
The d-block elements are placed in groups 3-12 and F-block elements with 4f and 5f orbital filled progressively. The general electronic configuration of d block elements and f- block elements are (n-1) d 1-10 ns 1-2 and (n-2) f 1-14 (n-1) d1 ns2 respectively. They are commonly known as transition elements because they exhibit multiple oxidation states because of the d-d transition which is possible by the availability of vacant d orbitals in these elements.
They have variable Oxidation States as well as are good catalysts because they provide a large surface area for the absorption of reaction. They show variable oxidation states to form intermediate with reactants easily. They are mostly lanthanoids and show lanthanoid contraction. Since differentiating electrons enter in an anti-penultimate f subshell. Therefore, these elements are also called inner transition elements.
Read More: The d and f block elements