Choose the transfer function that best fits the output response to a unit step input change shown in the figure:

Step 1: Analyze the Transfer Function Configuration.
The presence of a zero and a time delay along with the squared second pole in this configuration provides a dynamic response that begins with a delayed start, quickly rises, overshoots, and then settles, matching the behavior observed in the response curve.
Step 2: Explain the Fitting Criteria.
The time delay (\(e^{-\theta s}\)) accounts for the initial pause before the response begins.
The zero (\(as + 1\)) enhances the system's response speed post-delay.
The squared pole term \((\tau_2 s + 1)^2\) introduces the necessary damping to control the overshoot and allows the system to settle at a new steady state efficiently.
Consider the unity-negative-feedback system shown in Figure (i) below, where gain \( K \geq 0 \). The root locus of this system is shown in Figure (ii) below.
For what value(s) of \( K \) will the system in Figure (i) have a pole at \( -1 + j1 \)?

Consider a message signal \( m(t) \) which is bandlimited to \( [-W, W] \), where \( W \) is in Hz. Consider the following two modulation schemes for the message signal:
• Double sideband-suppressed carrier (DSB-SC): \[ f_{DSB}(t) = A_c m(t) \cos(2\pi f_c t) \] • Amplitude modulation (AM): \[ f_{AM}(t) = A_c \left( 1 + \mu m(t) \right) \cos(2\pi f_c t) \] Here, \( A_c \) and \( f_c \) are the amplitude and frequency (in Hz) of the carrier, respectively. In the case of AM, \( \mu \) denotes the modulation index. Consider the following statements:
(i) An envelope detector can be used for demodulation in the DSB-SC scheme if \( m(t)>0 \) for all \( t \).
(ii) An envelope detector can be used for demodulation in the AM scheme only if \( m(t)>0 \) for all \( t \).
Which of the following options is/are correct?
A controller \( D(s) \) of the form \( (1 + K_D s) \) is to be designed for the plant \[ G(s) = \frac{1000\sqrt{2}}{s(s+10)^2} \] as shown in the figure. The value of \( K_D \) that yields a phase margin of \(45^\circ\) at the gain cross-over frequency of 10 rad/sec is _____________ (round off to one decimal place). 
An ideal monoatomic gas is contained inside a cylinder-piston assembly connected to a Hookean spring as shown in the figure. The piston is frictionless and massless. The spring constant is 10 kN/m. At the initial equilibrium state (shown in the figure), the spring is unstretched. The gas is expanded reversibly by adding 362.5 J of heat. At the final equilibrium state, the piston presses against the stoppers. Neglecting the heat loss to the surroundings, the final equilibrium temperature of the gas is __________ K (rounded off to the nearest integer).
The residence-time distribution (RTD) function of a reactor (in min$^{-1}$) is 
The mean residence time of the reactor is __________ min (rounded off to 2 decimal places).}
Ideal nonreacting gases A and B are contained inside a perfectly insulated chamber, separated by a thin partition, as shown in the figure. The partition is removed, and the two gases mix till final equilibrium is reached. The change in total entropy for the process is _________J/K (rounded off to 1 decimal place).
Given: Universal gas constant \( R = 8.314 \) J/(mol K), \( T_A = T_B = 273 \) K, \( P_A = P_B = 1 \) atm, \( V_B = 22.4 \) L, \( V_A = 3V_B \).
The following data is given for a ternary \(ABC\) gas mixture at 12 MPa and 308 K:
\(y_i\): mole fraction of component \(i\) in the gas mixture
\(\hat{\phi}_i\): fugacity coefficient of component \(i\) in the gas mixture at 12 MPa and 308 K
The fugacity of the gas mixture is __________ MPa (rounded off to 3 decimal places).