Question:

Choose the correct option for graphical representation of Boyle’s law, which shows a graph of pressure vs. volume of a gas at different temperatures

Updated On: Nov 13, 2025
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The Correct Option is A

Solution and Explanation

To determine the correct graphical representation of Boyle's Law, we must first understand the principle of the law itself. Boyle's Law states that for a given mass of gas at constant temperature, the volume of the gas is inversely proportional to its pressure. Mathematically, this is expressed as:

\(P \propto \frac{1}{V} \quad \text{or} \quad PV = \text{constant} \)

This implies that if you were to plot pressure (P) against volume (V), the graph would be a hyperbola. When different temperature curves are considered, these are called isotherms, and each curve corresponds to a different constant temperature.

Let's analyze each graph option provided:

  • Option 1: This graph shows hyperbolic curves as the pressure decreases with an increase in volume, and it includes multiple curves for different temperatures. This correctly represents Boyle's Law.
  • Option 2: This graph does not appear to represent the inverse relationship characteristic of Boyle's Law.
  • Option 3: This graph again does not show the required hyperbolic relationship.
  • Option 4: Similar to options 2 and 3, this graph fails to illustrate the correct inverse relationship between pressure and volume.

Therefore, the correct choice for the graphical representation of Boyle's Law (pressure vs. volume at different temperatures) is:

Conclusion: Option 1 correctly illustrates Boyle's Law, with pressure decreasing as volume increases for different temperatures, shown as a series of hyperbolic curves.

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Concepts Used:

Gas Laws

The gas laws were developed at the end of the 18th century, when scientists began to realize that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.

The five gas laws are:

  • Boyle’s Law, which provides a relationship between the pressure and the volume of a gas.
  • Charles’s Law, which provides a relationship between the volume occupied by a gas and the absolute temperature.
  • Gay-Lussac’s Law, which provides a relationship between the pressure exerted by a gas on the walls of its container and the absolute temperature associated with the gas.
  • Avogadro’s Law, which provides a relationship between the volume occupied by a gas and the amount of gaseous substance.
  • The Combined Gas Law (or the Ideal Gas Law), which can be obtained by combining the four laws listed above.