Step 1: Calculate LSB: For an n-bit DAC with a full-scale output voltage of V, the least significant bit (LSB) voltage is given by:
\[
LSB = \frac{V}{2^n} = \frac{10}{2^{12}} = \frac{10}{4096} = 0.00244 V = 2.44 mV
\]
Step 2: Calculate MSB: The most significant bit (MSB) value is half of the total output voltage, which is 5V for the total range of 10V.
\[
MSB = \frac{V}{2} = \frac{10}{2} = 5V
\]
Therefore, LSB = 2.4 mV and MSB = 5 V.