Baeyer's reagent is a cold, dilute, alkaline solution of potassium permanganate KMnO4.
It is a powerful oxidizing agent and is used as a test for unsaturation (presence of double or triple bonds) in organic compounds. The permanganate ion MnO4- is a deep purple color.
When it reacts with an unsaturated compound, the purple color disappears, and a brown precipitate of manganese dioxide MnO2 forms. This decolorization of the permanganate solution is a positive test for unsaturation. It's important that the solution be cold and dilute; otherwise, the reaction may proceed too vigorously, and the permanganate may oxidize the organic compound further.
List-I | List-II | ||
(A) | [Co(NH3)5(NO2)]Cl2 | (I) | Solvate isomerism |
(B) | [Co(NH3)5(SO4)]Br | (II) | Linkage isomerism |
(C) | [Co(NH3)6] [Cr(CN)6] | (III) | Ionization isomerism |
(D) | [Co(H2O)6]Cl3 | (IV) | Coordination isomerism |