At 300 K, for the reaction A → P, the ∆Ssys is 5 J K-1 mol-1. What is the heat absorbed (in kJ mol-1) by the system?
Step 1: Using the relation between heat and entropy
- From thermodynamics, \[ q = T \Delta S_{sys} \] where \( q \) is heat absorbed, \( T \) is temperature, and \( \Delta S \) is entropy change.
Step 2: Substituting values \[ q = (300 K) \times (5 J K^{-1} mol^{-1}) \] \[ = 1500 J mol^{-1} \] \[ = 1.5 \text{ kJ mol}^{-1} \]
The rate of a reaction:
A + B −→ product
is given below as a function of different initial concentrations of A and B.
Experiment | \([A]\) (mol L\(^{-1}\)) | \([B]\) (mol L\(^{-1}\)) | Initial Rate (mol L\(^{-1}\) min\(^{-1}\)) |
---|---|---|---|
1 | 0.01 | 0.01 | \(5 \times 10^{-3}\) |
2 | 0.02 | 0.01 | \(1 \times 10^{-2}\) |
3 | 0.01 | 0.02 | \(5 \times 10^{-3}\) |