Assertion (A): [Cr(H_2O)_6]Cl_2 and [Fe(H_2O)_6]Cl_2 are examples of homoleptic complexes. Reason (R): All the ligands attached to the metal are the same.
Assertion (A) is false, but Reason (R) is true.
Step 1: Understanding homoleptic complexes. Homoleptic complexes are those in which all the ligands attached to the central metal atom are the same. Both \([Cr(H_2O)_6]Cl_2\) and \([Fe(H_2O)_6]Cl_2\) are examples of homoleptic complexes, as all the ligands in each complex are water molecules.
Step 2: Conclusion. Since Assertion (A) is true, and Reason (R) correctly explains it, the correct answer is option (A). \vspace{10pt}
Match the LIST-I with LIST-II
Choose the correct answer from the options given below:
Given below are two statements:
Statement I: A homoleptic octahedral complex, formed using monodentate ligands, will not show stereoisomerism
Statement II: cis- and trans-platin are heteroleptic complexes of Pd.
In the light of the above statements, choose the correct answer from the options given below
Match the following List-I with List-II and choose the correct option: List-I (Compounds) | List-II (Shape and Hybridisation) (A) PF\(_{3}\) (I) Tetrahedral and sp\(^3\) (B) SF\(_{6}\) (III) Octahedral and sp\(^3\)d\(^2\) (C) Ni(CO)\(_{4}\) (I) Tetrahedral and sp\(^3\) (D) [PtCl\(_{4}\)]\(^{2-}\) (II) Square planar and dsp\(^2\)
The correct IUPAC name of \([ \text{Pt}(\text{NH}_3)_2\text{Cl}_2 ]^{2+} \) is: