Question:

Assertion (A): [Cr(H_2O)_6]Cl_2 and [Fe(H_2O)_6]Cl_2 are examples of homoleptic complexes. Reason (R): All the ligands attached to the metal are the same.

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Homoleptic complexes contain only one type of ligand bound to the central metal atom.
  • Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
  • Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
  • Assertion (A) is true, but Reason (R) is false.
  • Assertion (A) is false, but Reason (R) is true. 
     

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The Correct Option is A

Solution and Explanation

Step 1: Understanding homoleptic complexes. Homoleptic complexes are those in which all the ligands attached to the central metal atom are the same. Both \([Cr(H_2O)_6]Cl_2\) and \([Fe(H_2O)_6]Cl_2\) are examples of homoleptic complexes, as all the ligands in each complex are water molecules. 

Step 2: Conclusion. Since Assertion (A) is true, and Reason (R) correctly explains it, the correct answer is option (A). \vspace{10pt}

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