Step 1: Analyze Assertion (A).
The ray is incident normally on the first face of the prism (\( i_1 = 0 \)), so the angle of refraction \( r_1 = 0 \). At the second face, the angle of incidence is \( r_2 = A \) (where \( A \) is the prism angle). For the emergent ray to graze the second face, the angle of emergence \( e = 90^\circ \). By Snell’s law at the second face:
\[
n \sin r_2 = \sin e \quad \Rightarrow \quad n \sin A = 1 \quad \Rightarrow \quad \sin A = \frac{1}{n}
\]
The critical angle \( \theta_c \) at the glass-air interface is:
\[
\sin \theta_c = \frac{1}{n}
\]
The assertion states \( \theta_c = A \), so \( \sin \theta_c = \sin A \), which holds when \( \sin A = \frac{1}{n} \). Thus, the emergent ray grazes the second face when \( A = \theta_c \), making Assertion (A) true.
Step 2: Analyze Reason (R).
The refractive index \( n \) of the prism material is a property of the material and depends on the wavelength of light, not on the prism angle \( A \). The angle \( A \) is a geometrical property of the prism, and \( n \) is independent of it. Thus, Reason (R) is false.
Step 3: Conclusion.
Assertion (A) is true, but Reason (R) is false, so the correct option is (C).