The notation $_{13}^{27}X$ tells us that the element X has an atomic number of 13. The atomic number corresponds to the number of protons and, in a neutral atom, also the number of electrons. Element 13 is aluminum (Al).
Aluminum is in group 13 of the periodic table. Elements in group 13 have 3 valence electrons. To achieve a stable electron configuration, aluminum tends to lose these 3 valence electrons. When an atom loses electrons, it becomes a positively charged ion (a cation).
Since aluminum loses 3 electrons, its charge becomes +3.
From the given following (A to D) cyclic structures, those which will not react with Tollen's reagent are : 
Compound 'P' undergoes the following sequence of reactions : (i) NH₃ (ii) $\Delta$ $\rightarrow$ Q (i) KOH, Br₂ (ii) CHCl₃, KOH (alc), $\Delta$ $\rightarrow$ NC-CH₃. 'P' is : 
