(i) Phenol \((C_6H_5OH)\) has the polar group -OH and non-polar group \(-C_6H_5\). Thus, phenol is partially soluble in water.
(ii) Toluene \((C_6H_5-CH_3)\) has no polar groups. Thus, toluene is insoluble in water.
(iii) Formic acid (HCOOH) has the polar group -OH and can form H-bond with water. Thus, formic acid is highly soluble in water.
(iv) Ethylene glycol has polar -OH group and can form H-bond. Thus, it is highly soluble in water.
(v) Chloroform is insoluble in water.
(vi) Pentanol \((C_5H_{11}OH)\) has polar -OH group, but it also contains a very bulky non-polar \(-C_5H_{11}\) group. Thus, pentanol is partially soluble in water.