Among the following hydrocarbon(s), how many of them would give rise to three groups of proton NMR peaks with 2:2:3 integration ratio? 
Step 1: Understanding proton NMR.
In proton NMR (nuclear magnetic resonance), the chemical shifts and integration ratios of the peaks provide information about the number and types of protons in a molecule. The integration ratio reflects the relative number of protons in different environments. A 2:2:3 integration ratio corresponds to three sets of protons with relative ratios of 2 protons, 2 protons, and 3 protons.
Step 2: Conclusion.
The correct answer is 2 because two of the given hydrocarbons will give rise to a 2:2:3 integration ratio in proton NMR.

The UV-visible spectrum of [Ni(en)\(_3\)]\(^{2+}\) (en = ethylenediamine) shows absorbance maxima at 11200 cm\(^{-1}\), 18350 cm\(^{-1}\), and 29000 cm\(^{-1}\).

[Given: Atomic number of Ni = 28] The correct match(es) between absorbance maximum and electronic transition is/are
One mole of a monoatomic ideal gas starting from state A, goes through B and C to state D, as shown in the figure. Total change in entropy (in J K\(^{-1}\)) during this process is ............... 
The number of chiral carbon centers in the following molecule is ............... 
A tube fitted with a semipermeable membrane is dipped into 0.001 M NaCl solution at 300 K as shown in the figure. Assume density of the solvent and solution are the same. At equilibrium, the height of the liquid column \( h \) (in cm) is ......... 