Question:
Among (a) - (d), the complexes that can display geometrical isomerism are :
$\left(a\right)\,\left[Pt\left(NH_{3}\right)_{3}Cl\right]^{+}$
$\left(b\right)\,\left[Pt\left(NH_{3}\right)Cl_{5}\right]^{-}$
$\left(c\right)\,\left[Pt\left(NH_{3}\right)_{2}Cl\left(NO\right)_{2}\right]$
$\left(d\right)\,\left[Pt\left(NH_{3}\right)_{4}ClBr\right]^{2+}$
Among (a) - (d), the complexes that can display geometrical isomerism are :
$\left(a\right)\,\left[Pt\left(NH_{3}\right)_{3}Cl\right]^{+}$
$\left(b\right)\,\left[Pt\left(NH_{3}\right)Cl_{5}\right]^{-}$
$\left(c\right)\,\left[Pt\left(NH_{3}\right)_{2}Cl\left(NO\right)_{2}\right]$
$\left(d\right)\,\left[Pt\left(NH_{3}\right)_{4}ClBr\right]^{2+}$
Updated On: Sep 24, 2024
- (d) and (a)
- (c) and (d)
- (a) and (b)
- (b) and (c)
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The Correct Option is B
Solution and Explanation
$[Pt(NH_3)_3Cl]^+\, \&\, [Pt(NH_3)Cl_5]^-$ does not show geometrical isomerism
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Concepts Used:
Coordination Compounds
A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.
Coordination entity:
A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.
Ligands:
A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.