1. Finding the Capacitance:
The capacitance \( C \) of a system is given by the formula:
\[ C = \frac{Q}{V} \]
Where:
From the given data:
Substituting the values into the formula:
\[ C = \frac{80 \times 10^{-6}}{16} = 5 \times 10^{-6} \, \text{F} = 5 \, \mu F \]
2. Capacitance with Dielectric Medium:
When a dielectric material of dielectric constant \( K \) is placed between the conductors, the capacitance increases by a factor of \( K \). The new capacitance \( C' \) is given by:
\[ C' = K \cdot C \]
Since the initial capacitance is \( C = 5 \, \mu F \), the new capacitance with the dielectric becomes:
\[ C' = K \cdot 5 \, \mu F \]
Now, the potential difference between the conductors will decrease because the capacitance has increased, while the charge remains the same. The new potential difference \( V' \) is given by:
\[ V' = \frac{Q}{C'} \]
Since \( C' = K \cdot C \), we have:
\[ V' = \frac{Q}{K \cdot C} = \frac{V}{K} \]
Therefore, the potential difference decreases by a factor of \( K \). If \( K \) is the dielectric constant of the material, the new potential difference is:
\[ V' = \frac{16}{K} \]
3. Effect of Changing the Charges on the Conductors:
When the charges on the conductors are changed to \( +160 \, \mu C \) and \( -160 \, \mu C \), the charge on each conductor becomes twice the original charge. However, the capacitance of a system depends only on the geometry of the system and the dielectric constant of the medium. The capacitance is independent of the charge on the conductors.
Therefore, the capacitance of the system remains the same at \( 5 \, \mu F \), and the potential difference will increase due to the increase in charge. The new potential difference \( V' \) can be found by:
\[ V' = \frac{Q'}{C} = \frac{160 \times 10^{-6}}{5 \times 10^{-6}} = 32 \, \text{V} \]
Conclusion:
(a) Calculate the standard Gibbs energy (\(\Delta G^\circ\)) of the following reaction at 25°C:
\(\text{Au(s) + Ca\(^{2+}\)(1M) $\rightarrow$ Au\(^{3+}\)(1M) + Ca(s)} \)
\(\text{E\(^\circ_{\text{Au}^{3+}/\text{Au}} = +1.5 V, E\)\(^\circ_{\text{Ca}^{2+}/\text{Ca}} = -2.87 V\)}\)
\(\text{1 F} = 96500 C mol^{-1}\)
Define the following:
(i) Cell potential
(ii) Fuel Cell
Calculate the emf of the following cell at 25°C:
\[ \text{Zn(s)} | \text{Zn}^{2+}(0.1M) || \text{Cd}^{2+}(0.01M) | \text{Cd(s)} \] Given: \[ E^\circ_{\text{Cd}^{2+}/\text{Cd}} = -0.40 \, V, \, E^\circ_{\text{Zn}^{2+}/\text{Zn}} = -0.76 \, V \] \[ [\log 10 = 1] \]