For a NaCl structure, the ratio of the radii of the cation and anion is approximately 0.5. Thus, the radius of the anion can be calculated as:
\[
r_{\text{anion}} = 2 \times r_{\text{cation}} = 2 \times 100 \, \text{pm} = 122.5 \, \text{pm}.
\]
Step 2: Conclusion.
The correct radius of the anion is \( 122.5 \, \text{pm} \), corresponding to option (c).