Question:

A solid compound XY has NaCl structure. If the radius of the cation is 100 pm, the radius of the anion \( Y^{1-} \) will be

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In ionic compounds with NaCl structure, the cation-to-anion radius ratio is approximately 0.5.
Updated On: Jan 6, 2026
  • 141.5 pm
  • 153.5 pm
  • 122.5 pm
  • 165.7 pm
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The Correct Option is C

Solution and Explanation

For a NaCl structure, the ratio of the radii of the cation and anion is approximately 0.5. Thus, the radius of the anion can be calculated as: \[ r_{\text{anion}} = 2 \times r_{\text{cation}} = 2 \times 100 \, \text{pm} = 122.5 \, \text{pm}. \]

Step 2: Conclusion.
The correct radius of the anion is \( 122.5 \, \text{pm} \), corresponding to option (c).
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