To find the percentage of volatile matter on a dry ash-free basis, we first calculate the weight of the dry, ash-free material. The total weight of the sample is 10 g. The weight of moisture and ash are given as 1 g and 2 g, respectively. The weight of the dry, ash-free material is:
\[
\text{Dry, ash-free material} = 10 - 1 - 2 = 7 \, \text{g}.
\]
The percentage of volatile matter on the dry ash-free basis is calculated as:
\[
\text{Percentage of volatile matter} = \frac{\text{Weight of volatile matter}}{\text{Weight of dry ash-free material}} \times 100
\]
Substitute the values:
\[
\text{Percentage of volatile matter} = \frac{5.6}{7} \times 100 = 80.0%.
\]
Thus, the percentage of volatile matter on the dry ash-free basis is \( \boxed{80.0} % \).