The de Broglie wavelength \( \lambda \) of a particle is given by the equation:
\[ \lambda = \frac{h}{p} = \frac{h}{\sqrt{2mE_k}} \]
where \( h \) is Planck's constant, \( p \) is the momentum, \( m \) is the mass of the particle, and \( E_k \) is the kinetic energy.
For a proton accelerated through a potential difference \( V \), the kinetic energy can be expressed as:
\[ E_k = eV \]
where \( e \) is the elementary charge.
Substituting \( E_k \) in the de Broglie equation:
\[ \lambda = \frac{h}{\sqrt{2meV}} \]
On doubling the accelerating potential to \( 2V \), the new wavelength \( \lambda' \) is given by:
\[ \lambda' = \frac{h}{\sqrt{2m \cdot 2eV}} = \frac{h}{\sqrt{4meV}} \]
This simplifies to:
\[ \lambda' = \frac{h}{2\sqrt{meV}} = \frac{\lambda}{\sqrt{2}} \]
Thus, the de Broglie wavelength decreases on doubling the accelerating potential. Therefore, the correct answer is "Decreases".