Given below are two statements. One is labelled as Assertion (A) and the other is labelled as Reason (R):
Assertion (A): In an insulated container, a gas is adiabatically shrunk to half of its initial volume. The temperature of the gas decreases.
Reason (R): Free expansion of an ideal gas is an irreversible and an adiabatic process.
In the light of the above statements, choose the correct answer from the options given below:
\( \text{M} \xrightarrow{\text{CH}_3\text{MgBr}} \text{N} + \text{CH}_4 \uparrow \xrightarrow{\text{H}^+} \text{CH}_3\text{COCH}_2\text{COCH}_3 \)
Identify the ion having 4f\(^6\) electronic configuration.