In simple harmonic motion (SHM), the total mechanical energy is conserved and is the sum of the kinetic energy \( K \) and potential energy \( U \).
The total energy \( E \) is constant and is given by: \[ E = K + U \] The total energy in SHM is also related to the amplitude \( A \) and is given by: \[ E = \frac{1}{2} m \omega^2 A^2 \] where \( m \) is the mass of the particle and \( \omega \) is the angular frequency.
Step 1: Kinetic Energy in SHM The kinetic energy \( K \) of the particle at a position \( x \) from the mean position is given by: \[ K = \frac{1}{2} m v^2 \] where \( v \) is the velocity of the particle at position \( x \). The velocity in SHM is related to the displacement by: \[ v = \omega \sqrt{A^2 - x^2} \] Thus, the kinetic energy becomes: \[ K = \frac{1}{2} m \omega^2 \left( A^2 - x^2 \right) \]
Step 2: Kinetic Energy at \( x = 0.707A \) At \( x = 0.707A \), the displacement is \( 0.707 \) times the amplitude. Substituting this into the expression for kinetic energy: \[ K = \frac{1}{2} m \omega^2 \left( A^2 - (0.707A)^2 \right) \] \[ K = \frac{1}{2} m \omega^2 \left( A^2 - 0.5A^2 \right) \] \[ K = \frac{1}{2} m \omega^2 \times 0.5A^2 \] \[ K = \frac{1}{4} m \omega^2 A^2 \] Since the total energy \( E = \frac{1}{2} m \omega^2 A^2 \), we have: \[ K = \frac{1}{2} E \] Thus, the kinetic energy at a distance of \( 0.707A \) from the mean position is \( \frac{E}{2} \).
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: