(a). A precipitation reaction occurs when two ionic solutions are mixed, and an insoluble compound (precipitate) is formed due to the exchange of ions. For example:
\[\text{BaCl}_2 \, (\text{aq}) + \text{Na}_2\text{SO}_4 \, (\text{aq}) \rightarrow \text{BaSO}_4 \, (\text{s}) + 2\text{NaCl} \, (\text{aq}).\]
Here, barium (\(\text{Ba}^{2+}\)) and sulfate (\(\text{SO}_4^{2-}\)) ions combine to form the insoluble compound \(\text{BaSO}_4\) (precipitate).
(b). Displacement Reaction: A more reactive element displaces a less reactive element from its compound.
Example:
\[\text{Zn (s)} + \text{CuSO}_4 \, (\text{aq}) \rightarrow \text{ZnSO}_4 \, (\text{aq}) + \text{Cu (s)}.\]
Double Displacement Reaction: Two ionic compounds exchange their ions to form new compounds.
Example:
\[\text{AgNO}_3 \, (\text{aq}) + \text{NaCl} \, (\text{aq}) \rightarrow \text{AgCl} \, (\text{s}) + \text{NaNO}_3 \, (\text{aq}).\]
For a reaction, \[ {N}_2{O}_5(g) \rightarrow 2{NO}_2(g) + \frac{1}{2} {O}_2(g) \] in a constant volume container, no products were present initially. The final pressure of the system when 50% of the reaction gets completed is:
In Carius method for estimation of halogens, 180 mg of an organic compound produced 143.5 mg of AgCl. The percentage composition of chlorine in the compound is ___________%. [Given: Molar mass in g mol\(^{-1}\) of Ag = 108, Cl = 35.5]