Question:

A gas is compressed isothermally to half its initial volume. The same gas is compressed separately through an adiabatic process until its volume is again reduced to half. Then :

Updated On: Apr 20, 2025
  • Compressing the gas through adiabatic process will require more work to be done.
  • Compressing the gas isothermally or adiabatically will require the same amount of work.
  • Which of the case (whether compression through isothermal or through adiabatic process) requires more work will depend upon the atomicity of the gas.
  • Compressing the gas isothermally will require more work to be done.
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The Correct Option is A

Solution and Explanation

Concept: 
When a gas is compressed, the work done depends on the nature of the thermodynamic process.

Isothermal Process:
In an isothermal process, the temperature remains constant. The work done in compressing a gas from volume $V_i$ to $V_f$ is:
\(W_{\text{iso}} = nRT \ln\left(\frac{V_i}{V_f}\right)\)

Adiabatic Process:
In an adiabatic process, there is no heat exchange. The work done is:
\(W_{\text{adi}} = \frac{P_i V_i - P_f V_f}{\gamma - 1}\)
or derived using:
\(W_{\text{adi}} = \frac{nR(T_i - T_f)}{\gamma - 1}\)
Key Point: In adiabatic compression, temperature rises, so internal energy increases → more work is required.

Since both compressions reduce the volume to half, we compare them:

  • Isothermal: Temperature constant → some heat leaves → less work needed.
  • Adiabatic: No heat exchange → temperature increases → internal energy increases → more work required.

Correct Answer:
\(\boxed{\text{Option 1: Compressing the gas through adiabatic process will require more work to be done.}}\)

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Concepts Used:

Thermodynamics

Thermodynamics in physics is a branch that deals with heat, work and temperature, and their relation to energy, radiation and physical properties of matter.

Important Terms

System

A thermodynamic system is a specific portion of matter with a definite boundary on which our attention is focused. The system boundary may be real or imaginary, fixed or deformable.

There are three types of systems:

  • Isolated System – An isolated system cannot exchange both energy and mass with its surroundings. The universe is considered an isolated system.
  • Closed System – Across the boundary of the closed system, the transfer of energy takes place but the transfer of mass doesn’t take place. Refrigerators and compression of gas in the piston-cylinder assembly are examples of closed systems.
  • Open System – In an open system, the mass and energy both may be transferred between the system and surroundings. A steam turbine is an example of an open system.

Thermodynamic Process

A system undergoes a thermodynamic process when there is some energetic change within the system that is associated with changes in pressure, volume and internal energy.

There are four types of thermodynamic process that have their unique properties, and they are:

  • Adiabatic Process – A process in which no heat transfer takes place.
  • Isochoric Process – A thermodynamic process taking place at constant volume is known as the isochoric process.
  • Isobaric Process – A process in which no change in pressure occurs.
  • Isothermal Process – A process in which no change in temperature occurs.

Laws of Thermodynamics

Zeroth Law of Thermodynamics

The Zeroth law of thermodynamics states that if two bodies are individually in equilibrium with a separate third body, then the first two bodies are also in thermal equilibrium with each other.

First Law of Thermodynamics 

The First law of thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes, distinguishing three kinds of transfer of energy, as heat, as thermodynamic work, and as energy associated with matter transfer, and relating them to a function of a body's state, called internal energy.

Second Law of Thermodynamics 

The Second law of thermodynamics is a physical law of thermodynamics about heat and loss in its conversion.

Third Law of Thermodynamics

Third law of thermodynamics states, regarding the properties of closed systems in thermodynamic equilibrium: The entropy of a system approaches a constant value when its temperature approaches absolute zero.