Question:

A first-order reaction has a half-life of 693 sec. What will be its rate constant?

Updated On: Mar 27, 2025
  • 0.001 sec-1
  • 1 sec-1
  • 0.01 sec-1
  • 0.1 sec-1
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The Correct Option is A

Solution and Explanation

For a first-order reaction, the relationship between the rate constant kkk and the half-life (t1/2t_{1/2}t1/2​) is given by the formula:

\(t_{1/2} = \frac{0.693}{k}\)

Where:

\(t_{1/2}\) is the half-life of the reaction.

\(k\) is the rate constant.

Given:

\(t_{1/2} = 693\) sec

We can solve for the rate constant \(k\):

\({t_{1/2}} = \frac{0.693}{693} = 0.001\ sec{−1}\)

Thus, the rate constant is 0.001 sec⁻¹, which corresponds to Option A.

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