For a completely mixed system, the rate constant \( k \) can be calculated using the following relationship:
\[
k = \frac{1}{HRT} \ln \left( \frac{C_0}{C_t} \right),
\]
where:
- \( HRT \) is the hydraulic retention time,
- \( C_0 \) is the initial BOD concentration,
- \( C_t \) is the concentration at time \( t \).
The total BOD\(_5\) reduction is 90 %, so the remaining BOD\(_5\) after treatment is 10 % of the initial concentration, i.e. \( C_t/C_0 = 0.1 \).
Thus, the equation becomes:
\[
k = \frac{1}{6} \ln \left( \frac{1}{0.1} \right) = \frac{1}{6} \ln(10) \approx 0.0347 \, \text{day}^{-1}.
\]
Thus, the rate constant for BOD\(_5\) removal is \( 0.35 \, \text{day}^{-1} \).