Event \(B\) indicates that the first throw is a 4 and the second throw is a 5. The probability of event \(B\) occurring is independent of event \(A\). Since the die is fair, the probability of rolling a 6 on any throw is \(\frac{1}{6}\).
Therefore, the probability of \(A\) given that \(B\) has already occurred is:
\[ P(A|B) = P(A) = \frac{1}{6}. \]