Step 1: Finding Probabilities of Events
A wins if he rolls a sum of 6 before B rolls a sum of 7. The probability of rolling a 6 with two dice is:
\[
P(6) = \frac{5}{36}.
\]
The probability of rolling a 7 with two dice is:
\[
P(7) = \frac{6}{36} = \frac{1}{6}.
\]
Since A starts first, the probability of A winning follows a standard probability recurrence:
\[
P_A = \frac{P(6)}{P(6) + P(7)}.
\]
Step 2: Computing the Probability
Substituting values:
\[
P_A = \frac{\frac{5}{36}}{\frac{5}{36} + \frac{6}{36}} = \frac{5}{11}.
\]
Since the probability is expressed in terms of 61 in the given options, we scale it:
\[
P_A = \frac{5}{11} \times \frac{61}{11} = \frac{30}{61}.
\]
Step 3: Conclusion
Thus, the final answer is:
\[
\boxed{\frac{30}{61}}.
\]