\[ \text{Relative Speed} = 65 + 35 = 100 \text{ km/h} \]
\[ \text{Time} = \frac{\text{Distance}}{\text{Speed}} = \frac{390}{100} = 3.9 \text{ hours} \]
The trains start at 10:00 a.m., and they take 3.9 hours to meet.
\[ 10:00 \text{ a.m.} + 3.9 \text{ hours} = 1:54 \text{ p.m.} \]
The trains will meet at 1:54 p.m..