The correct answer is (B):
Let the volume of the first and the second Solution be 100 and 300.
When they are mixed, quantity of ethanol in the mixture = (20 + 300S)
Let this Solution be mixed with equal volume i.e. 400 of third Solution in which the strength of ethanol is 20%
So, the quantity of ethanol in the final Solution
= (20 + 300S + 80) = (300S + 100)
It is given that, 31.25% of 800 = (300S + 100)
or, 300S + 100 = 250
or S = 1/2 = 50%
Hence, 50 is the correct answer.