Question:

2 L of $SO_2$ gas at 760 mm Hg are transferred to 10 L flask containing oxygen at a particular temperature, the partial pressure of $SO_2$ in the flask is

Updated On: Jun 24, 2024
  • 63.33 mm Hg
  • 152 mm Hg
  • 760 mm Hg
  • 1330 mm Hg
Hide Solution
collegedunia
Verified By Collegedunia

The Correct Option is B

Approach Solution - 1

$pSO_2 = \frac{P \times V}{V_{Total}} = \frac{760 \times 2000}{10000} $ = 152 mm Hg
Was this answer helpful?
0
1
Hide Solution
collegedunia
Verified By Collegedunia

Approach Solution -2

Given:
- Volume of \(SO_2\) gas initially = 2 L
- Pressure of \(SO_2\) gas initially = 760 mm Hg
- Total volume of the flask after transfer = 10 L

Convert the initial pressure of \(SO_2\) gas to atm:
\(P_{SO_2} = 760 \text{ mm Hg} \times \frac{1 \text{ atm}}{760 \text{ mm Hg}} = 1 \text{ atm}\)

Apply Dalton's Law of Partial Pressures:
According to Dalton's Law, the total pressure in the flask \(P_{\text{total}}\) is the sum of the partial pressures of \(SO_2\) and \(O_2\):
\(P_{\text{total}} = P_{SO_2} + P_{\text{O}_2}\)

Calculate the partial pressure of \(SO_2\) in the flask:
Initially, \(SO_2\) gas was at 1atm and was transferred to a total volume of 10 L.
Since \(SO_2\) gas and \(O_2\) gas are ideal gases and assuming no chemical reaction or significant temperature change, the partial pressure of \(SO_2\) after transfer can be approximated by the ratio of its initial volume to the total volume:

\(P_{SO_2, \text{final}} = P_{SO_2} \times \frac{V_{SO_2}}{V_{\text{total}}}\)

\(P_{SO_2, \text{final}} = 1 \text{ atm} \times \frac{2 \text{ L}}{10 \text{ L}}\)

\(P_{SO_2, \text{final}} = 1 \text{ atm} \times 0.2\)
\(P_{SO_2, \text{final}} = 0.2 \text{ atm}\)

Convert the final pressure of \(SO_2\) gas to mm Hg (since the options are in mm Hg):
\(P_{SO_2, \text{final}} = 0.2 \text{ atm} \times 760 \text{ mm Hg/atm}\)

\(P_{SO_2, \text{final}} = 152 \text{ mm Hg}\)

So, the correct option is (B): \(152 \text{ mm Hg}\)

Was this answer helpful?
0
0

Concepts Used:

States of Matter

The matter is made up of very tiny particles and these particles are so small that we cannot see them with naked eyes.

There are three States of Matter:

The three states of matter are as follows:

Solid State:

  • The solid-state is one of the fundamental states of matter.
  • Solids differ from liquids and gases by the characteristic of rigidity.
  • The molecules of solids are tightly packed because of strong intermolecular forces; they only oscillate about their mean positions.

Liquid State:

  • The molecules in a liquid are closely packed due to weak intermolecular forces.
  • These forces are weaker than solids but stronger than that of gases.
  • There is much space in between the molecules of liquids which makes their flowing ability easy.

Gaseous State:

  • In this state of matter, distances between the molecules are large (intermolecular distance is in the range of 10-7-10-5 cm.
  • The intermolecular forces experienced between them are negligible.
  • Thus, translatory, rotatory and vibratory motions are observed prominently in gases.