List of top Chemistry Questions asked in Indian Institute Of Technology Joint Admission Test for MSc

The diastereomeric pair(s) among the following option(s) is/are 

The compound(s) formed as intermediate(s) in the following reaction sequence is/are 

The increasing order of acidity of the given molecules in aqueous media is 

The correct option for the product(s) of the following reaction is 

 

The major product of the following reaction is 

In the following reaction of (D)-Glucose, a product P is formed.

Among the following compounds, the one which will give the same product (P) under identical reaction conditions is 
 

In 1H NMR spectrum of the given molecule, the correct order of chemical shifts of the labelled protons (H$^X$, H$^Y$, H$^Z$) is 

The major product of the following reaction is 


 

The observed magnetic moments of octahedral Mn$^{3+}$, Fe$^{3+}$ and Co$^{3+}$ complexes are 4.95, 6.06 and 0.00 BM, respectively. The correct option for the electronic configuration of Mn$^{3+}$, Fe$^{3+}$ and Co$^{3+}$ metal ions in these complexes, respectively, is

The correct trend in the rate of substitution of Cl$^-$ by pyridine in the following complexes is 

The complementary strand for the following single strand of DNA is 

The major product formed in the following reaction is 

The correct option for the major products of the following reaction is 

The correct order of wavelength ($\lambda_{max}$) of the halide to metal charge-transfer band of [Co(NH$_3$)$_5$Cl]$^{2+}$ (I), [Co(NH$_3$)$_5$Br]$^{2+}$ (II) and [Co(NH$_3$)$_5$I]$^{2+}$ (III), is
For a reaction of the type A + B $\rightarrow$ Products, the unit of the rate constant is mol L$^{-1}$ s$^{-1}$. The overall order of the reaction is
Given that the radius of the first Bohr orbit of hydrogen atom is 53 pm, the radius of its third Bohr orbit is ................ pm. (Round off to the nearest integer)
Assume that the reaction of MeMgBr with ethylacetate proceeds with 100% conversion to give tert-butanol. The volume of 0.2 M solution of MeMgBr required to convert 10 mL of a 0.025 M solution of ethylacetate to tert-butanol is ................ mL. (Round off to one decimal place)
A radioactive sample decays to 10% of its initial amount in 4600 minutes. The rate constant of this process is ................ hour\(^{-1}\). (Round off to two decimal places)
The collision flux of a monoatomic gas on copper surface is \(3.0 \times 10^{18}\) m\(^-2\) s\(^{-1}\). Note that copper surface forms a square lattice with lattice constant of 210 pm. If the sticking coefficient of the atom with copper is 1.0, the time taken by the gas to form a complete monolayer on the surface is ................ s. (Round off to one decimal place)
The ionization energy of hydrogen atom is 13.6 eV and the first ionization energy of sodium atom is 5.1 eV. The effective nuclear charge experienced by the valence electron of sodium atom is ................. (Round off to one decimal place)
The value of \(n\) for the complex [Fe(CO)\(_4\)(SiMe\(_3\))]^\(n\) satisfying the 18-electron rule is ................
In the structure of P\(_4\)O\(_{10}\), the number of P-O-P bond(s) is ................
Number of vertices in an icosahedral closo-borane is ................
The magnetic field strength required to excite an isolated proton to its higher spin state with an electromagnetic radiation of 300 MHz is ................ Tesla. (Round off to two decimal places)
\text{[Magnetogyric ratio of proton is } 26.75 \times 10^7 \text{ rad T}^{-1} \text{ s}^{-1}]
One liter of a buffer solution contains 0.004 mole of acetic acid (pK\(_a\) = 4.76) and 0.4 mole of sodium acetate. The pH of the solution is ................. (Round off to two decimal places)