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Chemistry
List of top Chemistry Questions
The maximum number of electrons in the shell with principal quantum number
$n$
is equal to
$2n^{2}$
. Two electrons can have the same value of three quantum numbers
$n,l$
and
$m_{b}$
but must have the opposite spin quantum number.
Chemistry
Structure of atom
The maximum oxidation state of chromium in its compounds is
$+6$
. Chromium has only six electrons in
$ns$
and
$(n - 1)d$
orbitals.
Chemistry
d -and f -Block Elements
The gases show ideal behaviour when the volume occupied is large so that the volume of the molecules can be neglected in comparison to it. The behaviour of the gas becomes more ideal when pressure is very low.
Chemistry
States of matter
The dipole moment in case of
$BeF_2$
is zero. The two equal bond dipoles point in opposite directions and cancel the effect of each other.
Chemistry
Chemical bonding and molecular structure
The characteristics of cathode rays do not depend upon the material of electrodes and the nature of the gas present in the cathode ray tube. Cathode rays consist of negatively charged particles, called electrons.
Chemistry
Structure of atom
The atomic size generally increases across a period and decreases down the group. Atomic size depends upon valence shell electronic configuration.
Chemistry
Classification of elements and periodicity in properties
Superoxides of alkali metals are paramagnetic. Superoxides contain
$O_2^-$
ion which has one unpaired electron.
Chemistry
GROUP 1 ELEMENTS
Soluble fluoride is often added to drinking water to bring its concentration up to
$1\, ppm$
.
$F^{-}$
ion concentration above
$2 \,ppm$
causes brown mottling of teeth.
Chemistry
Environmental Chemistry
$SiC$
has higher melting point than
$NaCl$
.
$SiC$
has stronger electrostatic forces of attraction.
Chemistry
The solid state
Quartz glass is crystalline solid and quartz is an amorphous solid. Quartz glass has long range order.
Chemistry
The solid state
Purine bases present in
$DNA$
are adenine and guanine. The base thymine is present in
$RNA$
while base uracil is present in
$DNA$
.
Chemistry
Biomolecules
$pK_a$
value of phenol is
$10.0$
while that of ethanol is
$15.9$
Ethanol is stronger acid than phenol.
Chemistry
Alcohols, Phenols and Ethers
$ PHBV$
is a biodegradable polymer.
$ PHBV$
is an aliphatic polyester.
Chemistry
Polymers
Oxidation state of oxygen in
$OF_{2}$
and
$Na_{2}O$
is
$+2$
and
$-2$
respectively. Oxygen is an electronegative element.
Chemistry
Classification of elements and periodicity in properties
$O_{2}$
molecule is diamagnetic while
$C_{2}$
molecule is paramagnetic in nature. Bond order of
$O_ 2$
molecule is
$1.5$
and that of
$C_2$
molecule is
$2.5$
.
Chemistry
Chemical bonding and molecular structure
$Na_{2}O$
is basic oxide whereas
$Cl_{2}O_{7}$
is acidic oxide. Elements on extreme left form basic oxides whereas elements on extreme right form acidic oxides.
Chemistry
Classification of elements and periodicity in properties
Lyophilic colloids have a unique property of protecting lyophobic colloids. Lyophilic colloids are extensively solvated.
Chemistry
Surface Chemistry
Lithium salts are mostly hydrated. The hydration enthalpies of alkali metal ions decrease with increase in ionic sizes.
Chemistry
GROUP 1 ELEMENTS
$K_4[Fe(CN)_6]$
is diamagnetic and
$[Fe(H_2O)_6 ]Cl_3$
is paramagnetic. Hybridisation of central metal m
$K_4[Fe(CN)_6] is \,sp^3d^2,$
while in
$[Fe(H_2O)_6]Cl_3\, is\, d^2\, sp^3$
Chemistry
coordination compounds
Isocyanide test can be used to distinguish between secondary and tertiary amines. Tertiary amines on heating with chloroform and ale.
$KOH$
form foul smelling substances.
Chemistry
Amines
In the series
$Sc$
to
$Zn$
, the enthalpy of atomisation of zinc is the lowest. Zinc has greater number of unpaired electrons.
Chemistry
d -and f -Block Elements
In vapour state sulphur is paramagnetic in nature. In vapour state sulphur exists as
$S_2$
molecule.
Chemistry
p -Block Elements
In the metallury of aluminium, purified
$Al_2O_3$
is mixed with
$Na_3AlF_6$
or
$CaF_2$
.
$Na_3AlF_6$
or
$CaF_2$
lowers the melting point of mixture and increases its conductivity.
Chemistry
General Principles and Processes of Isolation of Elements
In the presence of alkaline
$KMnO_{4} 4-$
methylacetophenone is oxidised to benzoic acid. Keto group is oxidised to
$??OOH$
group.
Chemistry
Aldehydes, Ketones and Carboxylic Acids
In the reaction,
$2Cu_{2}O_{\left(s\right)}+Cu_{2}S_{\left(s\right)} \rightarrow 6 Cu_{\left(s\right)}+SO_{2\left(g\right)}$
copper acts as a reductant and sulphur acts as an oxidant. The given reaction is not a redox reaction.
Chemistry
Redox reactions
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