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Chemistry
List of top Chemistry Questions asked in AIIMS
N?? bond length is minimum in
AIIMS - 2012
AIIMS
Chemistry
Bond Parameters
Magnetic moment of
$Cr^{2+}$
is nearest to
AIIMS - 2012
AIIMS
Chemistry
d -and f -Block Elements
In Bohr?? orbit,
$\frac{nh}{2\pi}$
indicates
AIIMS - 2012
AIIMS
Chemistry
Structure of atom
If
$Si$
is doped with
$B$
,
AIIMS - 2012
AIIMS
Chemistry
The solid state
Etherates are
AIIMS - 2012
AIIMS
Chemistry
Ethers
$CsCl$
has
$bcc$
arrangement. Its unit cell edge length is
$400\,pm$
. Its inter-ionic distance is
AIIMS - 2012
AIIMS
Chemistry
The solid state
But-1-ene
$ { ->[{(CH_3COO)_2Hg}][{H_3O^+}] }$
? The product in the above reaction is
AIIMS - 2012
AIIMS
Chemistry
Alcohols, Phenols and Ethers
Bond dissociation energy of CH is 360 kJ/mol and CH is 620 kJ/mol. Then bond dissociation energy of C - C bond is
AIIMS - 2012
AIIMS
Chemistry
Thermodynamics
van-Arkel method is used to prepare samples of some metals. It involves reaction of
$CO$
with metals to form volatile carbonyls which decompose on heating to give pure metal.
AIIMS - 2012
AIIMS
Chemistry
Refining
The presence of nitro group facilitates nucleophilic substitution reactions in aryl halides. The intermediate carbanion is stabilised due to the presence of nitro group.
AIIMS - 2012
AIIMS
Chemistry
Chemical Reactions
The free gaseous Cr atom has six unpaired electrons. Half-filled s-orbital has greater stability.
AIIMS - 2012
AIIMS
Chemistry
properties of d block elements
Sodium acetate on Kolbe?? electrolysis gives methane. Methyl free radical is formed at cathode.
AIIMS - 2012
AIIMS
Chemistry
Hydrocarbons
Sodium carbonate extract of a salt containing sulphide ions gives a violet colour with appropriate reagent. The reagent sodium nitroprusside gives violet colour due to the formation of sodium thionitroprusside.
AIIMS - 2012
AIIMS
Chemistry
GROUP 1 ELEMENTS
Precipitation of soap is made by the addition of salt
$(NaCl)$
. Presence of common ion suppresses the dissociation of weak acid.
AIIMS - 2012
AIIMS
Chemistry
Ionic Equilibrium In Solution
Phenol is more reactive than benzene towards electrophilic substitution reaction. In the case of phenol, the intermediate carbocation is more resonance stabilised.
AIIMS - 2012
AIIMS
Chemistry
Alcohols, Phenols and Ethers
HC
$=$
C
$^{-}$
is more stable than HC
$=$
CH
$^{-}$
. HC
$=$
C
$^{-}$
has more s-character than HC
$=$
CH
$^{-}$
.
AIIMS - 2012
AIIMS
Chemistry
Hydrocarbons
$H_2Se$
is less acidic than
$H_2S$
.
$S$
is less electronegative than
$Se$
.
AIIMS - 2012
AIIMS
Chemistry
p -Block Elements
$[Fe(H_2O)_5NO]SO_4$
is paramagnetic. The
$Fe$
in
$[Fe(H_2O)_5NO]SO_4$
has three unpaired electrons.
AIIMS - 2012
AIIMS
Chemistry
coordination compounds
Diamond and graphite do not have the same crystal structure. Diamond is crystalline while graphite is amorphous.
AIIMS - 2012
AIIMS
Chemistry
p -Block Elements
$ClF_3$
has T-shape structure. It has two lone pairs arranged at 180
$^{\circ}$
angle.
AIIMS - 2012
AIIMS
Chemistry
Chemical bonding and molecular structure
$BF_3$
molecule is planar but
$NF_3$
is pyramidal. N atom is smaller than B.
AIIMS - 2012
AIIMS
Chemistry
Hybridisation
Four successive members of the first row transition elements are listed below with their atomic numbers. Which one of them is expected to have the highest third ionization enthalpy?
AIIMS - 2012
AIIMS
Chemistry
properties of d block elements
The aqueous solution containing which one of the following ions will be colourless? (Atomic number of
$Sc = 21, Fe = 26, Ti = 22, Mn = 25$
)
AIIMS - 2012
AIIMS
Chemistry
properties of d block elements
What is the correct relationship between the
$pHs$
of isomolar solutions of sodium oxide
$(pH_1)$
, sodium sulphide
$(pH_2)$
, sodium selenide
$(pH_3)$
and sodium telluride
$(pH_4)$
?
AIIMS - 2012
AIIMS
Chemistry
Acids and Bases
Which has the highest nucleophilicity?
AIIMS - 2012
AIIMS
Chemistry
Classification Of Organic Compounds
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