Question:

Zone refining is based on the principle that _________.

Updated On: Jul 7, 2022
  • impurities of low boiling metals can be separated by distillation
  • impurities are more soluble in molten metal than in solid metal
  • different components of a mixture are differently adsorbed on an adosrbent
  • vapours of volatile compound can be decomposed in pure metal
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The Correct Option is B

Solution and Explanation

Zone refining is based on the principle that the impurities are more soluble in molten state than in solid state of the metal. A circular mobile heater fixed at one end of impure metal rod. The molten zone moves along with heater which is moved forward As the heater moves forward, the pure metal crystallises out of the melt and the impurities pass on into adjacent molten zone. The process is repeated several times and the heater is moved in the same direction. At one end, impurities get concentrated. This end is cut off. e.g., germanium, silicon gallium etc., are refined by this method.
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Concepts Used:

General Principles and Processes of Isolation of Elements

What are Ores and Minerals? 

Minerals are the naturally occurring, homogeneous inorganic solid substances. They are having a definite chemical composition and crystalline structure, hardness and color. For example, copper pyrite, calamine, etc.

Impurities in an ore are called gauge. The removal of a gauge from the ore is called concentration ore. 

Several steps are involved in the extraction of pure metal from ores. Major steps are as follows –

  • Concentration of the ore
  • Isolation of the metal from its concentrated ore
  • Purification of the metal