| Point of Difference | Lanthanoids | Actinoids |
|---|---|---|
| Electronic configuration | Involve filling of 4f orbitals. | Involve filling of 5f orbitals. |
| Oxidation states | Show mainly +3 oxidation state, other states are less common. | Show variable oxidation states (+3 to +6 are common). |
| Radioactivity | Mostly non-radioactive (except promethium). | All actinoids are radioactive. |
| Occurrence | More abundant and occur naturally. | Mostly synthetic (except Th, Pa, U). |
| Chemical reactivity | Less reactive than actinoids. | More reactive, especially in finely divided form. |
| Complex formation | Less tendency to form complexes. | Greater tendency to form complexes due to higher oxidation states and larger ionic size. |
The main differences are based on orbital filling, oxidation states, radioactivity, occurrence, reactivity, and complex formation. In short: Lanthanoids = 4f series, mostly +3, non-radioactive; Actinoids = 5f series, variable oxidation states, all radioactive.