Atomic and Ionic Size: Across a period, atomic size slightly decreases due to poor shielding by d-electrons. Down a group, size increases due to the addition of a new energy level.
Ionization Enthalpy: Transition metals have higher ionization enthalpy due to their small size and nuclear attraction. \item Ionization energy does not increase significantly across the series because of screening effects.
The correct IUPAC name of \([ \text{Pt}(\text{NH}_3)_2\text{Cl}_2 ]^{2+} \) is:
What type of isomerism is shown by the complex \([\text{Co(NH}_3)_6][\text{Cr(CN)}_6]\)?
The given coordination compound \([\text{Co(NH}_3)_6][\text{Cr(CN)}_6]\) exhibits ionization isomerism.
**Explanation:** Ionization isomerism arises when two complexes have the same molecular formula but yield different ions in solution. In this case, the cationic complex \([\text{Co(NH}_3)_6]^{3+}\) and the anionic complex \([\text{Cr(CN)}_6]^{3-}\) could interchange their ligands under different conditions, leading to a different complex with distinct properties.
Write the IUPAC name of the following complex: \([\text{Co}(\text{NH}_3)_5(\text{CO}_3)]\text{Cl}\).