Atomic and Ionic Size: Across a period, atomic size slightly decreases due to poor shielding by d-electrons. Down a group, size increases due to the addition of a new energy level.
Ionization Enthalpy: Transition metals have higher ionization enthalpy due to their small size and nuclear attraction. \item Ionization energy does not increase significantly across the series because of screening effects.
The Crystal Field Theory (CFT) of coordination compounds is based on the effect of different crystal fields (provided by the ligands taken as point charges) on the degeneracy of d-orbital energies of the central metal atom/ion. The splitting of the d-orbitals provides different electronic arrangements in strong and weak crystal fields. In tetrahedral coordination entity formation, the d-orbital splitting is smaller as compared to the octahedral entity.
What is crystal field splitting energy?
The Crystal Field Theory (CFT) of coordination compounds is based on the effect of different crystal fields (provided by the ligands taken as point charges) on the degeneracy of d-orbital energies of the central metal atom/ion. The splitting of the d-orbitals provides different electronic arrangements in strong and weak crystal fields. In tetrahedral coordination entity formation, the d-orbital splitting is smaller as compared to the octahedral entity.
On the basis of CFT, explain why [Ti(H$_2$O)$_6$]Cl$_3$ complex is coloured? What happens on heating the complex [Ti(H$_2$O)$_6$]Cl$_3$? Give reason.
Find the values of \( x, y, z \) if the matrix \( A \) satisfies the equation \( A^T A = I \), where
\[ A = \begin{bmatrix} 0 & 2y & z \\ x & y & -z \\ x & -y & z \end{bmatrix} \]