Question:

Write balanced chemical equation of the reaction of ethanamine with NaNO\(_2\) + dil. HCl.

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Primary aliphatic amines liberate N\(_2\) gas on reaction with nitrous acid – useful for identification.
Updated On: Oct 7, 2025
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Solution and Explanation

Step 1: Nature of reaction.
Aliphatic primary amines react with nitrous acid to form alcohols, releasing nitrogen gas.
Step 2: Reaction.
Ethanamine + nitrous acid → Ethanol + N\(_2\) + H\(_2\)O.
Step 3: Conclusion.
Hence ethanamine gives ethanol by reaction with NaNO\(_2\)/HCl.
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